By Daniel Kleppner, Robert Kolenkow
Classical mechanics produces very exact effects in the area of daily event. it's outdated via relativistic mechanics for platforms relocating at huge velocities close to the rate of sunshine, quantum mechanics for platforms at small distance scales, and relativistic quantum box idea for structures with either houses.
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If for convenience we denote these monomer states as I a> and I p>, respectively, then broken symmetry kets will have fonos such as laap> == lal > la2 > IP3 > (20) which represents a state with Ms = 512 which can be approximately identified with a broken symmetry molecular orbital wavefunction that places five unpaired spin-up d-electrons on centers 1 and 2, and five spin-down d-electrons on center 3. These broken symmetry kets are not intended to approximate eigenstates of the Hamiltonian; rather, they represent mixed states whose energies can be computed by both spin-unrestricted molecular orbital and by spin Hamiltonian methods, so that the two may be compared.
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